A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids

Literature Information

Publication Date 2016-09-26
DOI 10.1039/C6CP05658J
Impact Factor 3.676
Authors

Carlos Franco, Núria Crivillers, Gonca Seber, Andrea Droghetti, Ivan Rungger, Ilya V. Pobelov, Jaume Veciana, Marta Mas-Torrent, Concepció Rovira


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Abstract

A redox-active persistent perchlorotriphenylmethyl (PTM) radical chemically linked to gold exhibits stable electrochemical activity in ionic liquids. Electrochemical tunnelling spectroscopy in this medium demonstrates that the PTM radical shows a highly effective redox-mediated current enhancement, demonstrating its applicability as an active nanometer-scale electronic component.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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