Photoinduced long-lived charge transfer excited states in AT-DNA strands
Literature Information
Lara Martinez-Fernandez, Yuyuan Zhang, Kimberly de La Harpe, Ashley A. Beckstead, Bern Kohler, Roberto Improta
The IR spectrum of a charge transfer (CT) excited electronic state in DNA has been computed for the first time, enabling assignment of the long-lived component of the transient IR spectrum of a d(AT)9 single strand to an A → T CT state. Experimentally, the CT state lifetime is much shorter than in the double strand, and our calculations explain this result using Marcus Theory.
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