A novel zinc based binary catalytic system for CO2 utilization under mild conditions
Literature Information
Publication Date
2016-01-07
DOI
10.1039/C5QO00356C
Impact Factor
5.281
Authors
Willi Desens, Christina Kohrt, Anke Spannenberg, Thomas Werner
View Original
Abstract
Herein we report the development of a novel binary catalytic system for the addition of CO2 to epoxides based on zinc iodide and an imidazolium salt. The influence of the nature of the imidazolium ion and the anion has been studied in a test reaction. The optimized system exhibits excellent activity and selectivity. Furthermore, the reaction can be performed under very mild (30 °C) and solvent free conditions yielding the desired cyclic carbonates in up to 99%.
Recommended Journals
Related Literature
Rapid, semi-automated convergent synthesis of low generation triazine dendrimers using microwave assisted reactions
Alan E. Enciso, Zachary M. Abid, Eric E. Simanek
2014-04-15
Paper
DOI: 10.1039/C4PY00349G
A water-soluble polymer for selective colorimetric sensing of cysteine and homocysteine with temperature-tunable sensitivity
A. Balamurugan, Hyung-il Lee
2014-05-19
Communication
DOI: 10.1039/C4PY00476K
Facile fabrication of reduction-responsive nanocarriers for controlled drug release
Rui Sun, Qiaojie Luo, Chen Gao, Ying Wang, Lilong Gao, Hong Du, Ying Huang, Xiaodong Li, Zhiquan Shen, Weipu Zhu
2014-06-03
Communication
DOI: 10.1039/C4PY00577E
Improvement of the control over SARA ATRP of 2-(diisopropylamino)ethyl methacrylate by slow and continuous addition of sodium dithionite
Joana R. Góis, Dominik Konkolewic, Anatoliy V. Popov, Tamaz Guliashvili, Krzysztof Matyjaszewski, Arménio C. Serra, Jorge F. J. Coelho
2014-05-13
Paper
DOI: 10.1039/C4PY00561A
ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp
Tao Zhang, Tao Chen, Ihsan Amin, Rainer Jordan
2014-04-01
Paper
DOI: 10.1039/C4PY00346B
Phosphazene-catalyzed ring-opening polymerization of ε-caprolactone: influence of solvents and initiators
Haleema Alamri, Junpeng Zhao, David Pahovnik, Nikos Hadjichristidis
2014-05-30
Paper
DOI: 10.1039/C4PY00493K
One-pot synthesis of POSS-containing alternating copolymers by RAFT polymerization and their microphase-separated nanostructures
Zhenghe Zhang, Lizhi Hong, Yun Gao, Weian Zhang
2014-04-07
Paper
DOI: 10.1039/C4PY00302K
The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP
Xiuyu Jiang, Xue Jiang, Guolin Lu, Chun Feng, Xiaoyu Huang
2014-05-20
Paper
DOI: 10.1039/C4PY00415A
Synthesis of end-functionalized boronic acid containing copolymers and their bioconjugates with rod-like viruses for multiple responsive hydrogels
2014-05-15
Paper
DOI: 10.1039/C4PY00508B
You might also like
Compound Q&A
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
858-46-82,4,6-Tris(pentafluo...
Compound Q&A
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
56787-36-1Chloroac-nle-oh
Compound Q&A
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
55095-15-3alpha-(2-Bromophenyl...
Compound Q&A
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
139585-48-12-Chloro-5-methoxypy...
Compound Q&A
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
12036-22-5Tungsten(IV) oxide
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.