Rapid, semi-automated convergent synthesis of low generation triazine dendrimers using microwave assisted reactions
Literature Information
Publication Date
2014-04-15
DOI
10.1039/C4PY00349G
Impact Factor
5.582
Authors
Alan E. Enciso, Zachary M. Abid, Eric E. Simanek
View Original
Abstract
Microwave assisted synthesis allows for the rapid access of low generation triazine dendrimers in high yields. Products include a macromonomer and alkyne functionalized dendrimers from generation one to three. Using a microwave assisted, convergent synthetic approach, two nucleophilic aromatic substitution reactions are executed on cyanuric chloride in 10 min at 60 째C using primary amines. Substitution of the resulting monochlorotriazine with a diamine requires 95 째C for 30 min. Purifications are accomplished using an automated chromatography system such that the generation three dendrimer can be prepared from the starting materials in less than one day.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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