Cobalt(ii)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions
Literature Information
Publication Date
2015-11-16
DOI
10.1039/C5QO00293A
Impact Factor
5.281
Authors
Ya-Fei Guo, Bao-Hua Xu, Ting Li, Lei Wang, Suo-Jiang Zhang
View Original
Abstract
The efficient cobalt(II) catalyzed oxidative alkoxylation of aldehydes, a method directly leading to the corresponding esters, is presented. Mechanism studies provide extensive insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion. The in situ generated hypoiodites (IO−/IO2−) mainly from conversion of I3− to IO3− account for a cooperative effect with the oxygen centered radical species to make the important hydrogen abstraction of hemiacetal intermediates more selective, thereby offering high efficiency.
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Organic Chemistry Frontiers
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