Polythiol copolymers with precise architectures: a platform for functional materials
Literature Information
Publication Date
2014-06-03
DOI
10.1039/C4PY00293H
Impact Factor
5.582
Authors
Morgane Le Neindre, Renaud Nicolaÿ
View Original
Abstract
The richness of thiol chemistry makes polythiol copolymers versatile building blocks for macromolecular and material engineering. This review presents the different synthetic routes to prepare polythiol copolymers, covering (co)polymerization of protected thiol monomers, (co)polymerization of unprotected thiol monomers and post-polymerization modification. Functionalization of polythiol copolymers using various pathways, such as thiol–ene reaction, thiol-Michael addition, thiol–disulfide exchange and metal–sulfur coordination is also illustrated as well as diverse (bio)applications, including self-healing materials, coatings, thiomers and hydrogels.
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Source Journal
Polymer Chemistry
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