Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions‡
Literature Information
Publication Date
2015-06-02
DOI
10.1039/C5PY00772K
Impact Factor
5.582
Authors
Jie Liu, John M. Tobin, Zhengtao Xu, Filipe Vilela
View Original
Abstract
A conjugated microporous polymer was synthesized via a modified Sonogashira–Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol–yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
trans-2-(2-Methoxyphenyl)-5-oxotetrahydrofuran-3-carboxylic acid
CAS Number:
99226-02-5
Molecular Formula:
C12H12O5
(R)-2-(Methylamino)propanoic acid hydrochloride
CAS Number:
1155878-14-0
Molecular Formula:
C4H10ClNO2
![4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure](https://static.chemtradehub.com/structs/362/3627-01-8-79ac.webp "4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure")
4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid
CAS Number:
3627-01-8
Molecular Formula:
C16H12N2O9S2
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