![5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure](https://static.chemtradehub.com/structs/888/888720-60-3-4f7c.webp "5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure")
Synthesis and characterization of innovative well-defined difluorophosphonylated-(co)polymers by RAFT polymerization
Literature Information
Publication Date
2015-05-13
DOI
10.1039/C5PY00690B
Impact Factor
5.582
Authors
Hien The Ho, Justine Coupris, Sagrario Pascual, Laurent Fontaine, Thierry Lequeux, Thi Nhàn Pham
View Original
Abstract
Reversible addition–fragmentation chain-transfer (RAFT) polymerization of a methacrylate derivative bearing a difluorophosphonylated moiety, namely diisopropyl 1,1-difluoro-5-methacryloyloxy-pentylphosphonate, was successfully achieved for the first time in the presence of 4-cyano-4-(thiobenzoylthio)pentanoic acid as the chain transfer agent. Polymers with various molecular weights and low dispersities were obtained in a controlled way. Additionally, a new chain transfer agent containing a difluorophosphonated moiety (pCF2-CTA) was successfully prepared to control the polymerization of methyl methacrylate and to create the pCF2 functionality at the poly(methyl methacrylate) chain-end by RAFT polymerization. The dealkylation of phosphonate ester polymers was performed with excellent yields using bromotrimethylsilane.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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![2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure](https://static.chemtradehub.com/structs/131/1312456-05-5-9a15.webp "2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure")
2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate
CAS Number:
1312456-05-5
Molecular Formula:
C12H20N2O3
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