Hydrophobically driven twist sense bias of hollow helical foldamers of aromatic hydrazide polymers in water

Literature Information

Publication Date 2015-02-11
DOI 10.1039/C5PY00129C
Impact Factor 5.582
Authors

Rong Guo, Liang Zhang, Hui Wang, Dan-Wei Zhang, Zhan-Ting Li


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Abstract

Three aryl hydrazide foldamer polymers, which bear different numbers of chiral pentaethylene glycol chains, have been synthesized. Circular dichroism and UV-vis studies reveal that two of them can be driven by hydrophobicity to form helical hollow conformation in water that exhibit strong twist sense bias.

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