Phase transition kinetics and surface binding states of methylammonium lead iodide perovskite

Literature Information

Publication Date 2016-02-09
DOI 10.1039/C5CP06232B
Impact Factor 3.676
Authors

G. Rajendra Kumar, A. Dennyson Savariraj, S. N. Karthick, S. Selvam, B. Balamuralitharan, Hee-Je Kim, K. K. Viswanathan, M. Vijaykumar


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Abstract

We have presented a detailed analysis of the phase transition kinetics and binding energy states of solution processed methylammonium lead iodide (MAPbI3) thin films prepared at ambient conditions and annealed at different elevated temperatures. It is the processing temperature and environmental conditions that predominantly control the crystal structure and surface morphology of MAPbI3 thin films. The structural transformation from tetragonal to cubic occurs at 60 째C with a 30 minute annealing time while the 10 minute annealed films posses a tetragonal crystal structure. The transformed phase is greatly intact even at the higher annealing temperature of 150 째C and after a time of 2 hours. The charge transfer interaction between the Pb 4f and I 3d oxidation states is quantified using XPS.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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