A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

Literature Information

Publication Date 2004-08-19
DOI 10.1039/B409463H
Impact Factor 6.222
Authors

Yu-Sheng Chen, Tim Graber


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Abstract

A very large Rh–Rh contraction of ∼0.85 Å occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.

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