Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes

Literature Information

Publication Date 2004-08-20
DOI 10.1039/B407229D
Impact Factor 6.222
Authors

John Fielden, De-Liang Long, Leroy Cronin


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Abstract

Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis,trans-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate syn-[Cu(DAHC)2F](F)·2CH3OH·H2O and red crystals of 4-coordinate anti-[Cu(DAHC)2](F)2·2H2O.

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