Ionic hydrogenation of C-20, 22-ketene dithioacetal: stereoselective synthesis of steroidal C (20R) aldehydes
Literature Information
Bapurao B. Shingate, Braja G. Hazra, Vandana S. Pore, Rajesh G. Gonnade, Mohan M. Bhadbhade
Homologation of 16-dehydropregnenolone acetate 7 leads to excellent stereocontrolled synthesis of unnatural C (20R) aldehydes 4 and 6 through compound 13.
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![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure 1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp)

