Photoinduced charge separation in an oligophenylenevinylene-based Hamilton-type receptor supramolecularly associating two C60-barbiturate guests
Literature Information
G. Pagona, A. Stergiou, H. B. Gobeze, G. Rotas, F. D'Souza, N. Tagmatarchis
The supramolecular association of an oligophenylene-vinylene (OPV)-based Hamilton-type receptor 1 with C60-barbiturate 2, via six hydrogen bonds per OPV terminal, forming C60/OPV/C60 complex 3 is presented. The particular host–guest motif expressed in 3 ensures strong interactions between the discrete components of the complex based on the multiple hydrogen bonding interactions as conveyed by an association constant greater than 105 M−1. Furthermore, femto- and nano-second transient absorption studies disclose photoinduced charge separation from 1OPV* to C60 within 9.4 ps. The observed ultrafast charge separation phenomena in the C60/OPV/C60 complex open up wide avenues toward the efficient construction of new materials for optoelectronic and solar cell applications.
Recommended Journals

Journal of Peptide Science

Current Opinion in Colloid & Interface Science

Organic Process Research & Development

Current Opinion in Solid State & Materials Science

Russian Journal of General Chemistry

Russian Chemical Bulletin

Saudi Pharmaceutical Journal

Nature Medicine

Russian Journal of Applied Chemistry

Chemistry Education Research and Practice
Related Literature
Evolution of nickel speciation during preparation of Ni–SiO2catalysts: effect of the number of chelating ligands in [Ni(en)x(H2O)6−2x]2+ precursor complexes
Ke-Qiang Sun, Eric Marceau, Michel Che
DOI: 10.1039/B513319J
Urethane cross-linked poly(oxyethylene)/siliceous nanohybrids doped with Eu3+ ions Part 1. Coordinating ability of the host matrix
Verónica de Zea Bermudez, Denis Ostrovskii, M. Cristina Gonçalves, Luís D. Carlos, Rute A. Sá Ferreira, Lucinda Reis, Per Jacobsson
DOI: 10.1039/B308201F
A comparison of water adsorption on ordered and disordered silica substrates
Joël Puibasset, Roland J.-M. Pellenq
DOI: 10.1039/B313001K
The nature of water on surfaces of laboratory systems and implications for heterogeneous chemistry in the troposphere
Ann Louise Sumner, Erik J. Menke, Yael Dubowski, John T. Newberg, Reginald M. Penner, John C. Hemminger, Lisa M. Wingen, Theo Brauers, Barbara J. Finlayson-Pitts
DOI: 10.1039/B308125G
Tricriticality in the ternary system 3-methylpyridine/water/NaBr? The coexistence curves
Monika Wagner, Olimpiu Stanga, Wolffram Schröer
DOI: 10.1039/B212337A
Exactly solvable approximating models for Rabi Hamiltonian dynamics
Andrey Pereverzev, Eric R. Bittner
DOI: 10.1039/B517470H
Structure and dynamics of the [Zn(NH3)(H2O)5]2+ complex in aqueous solution obtained by an ab initio QM/MM molecular dynamics study
M. Qaiser Fatmi, Thomas S. Hofer, Bernhard R. Randolf, Bernd M. Rode
DOI: 10.1039/B518223A
High-resolution IRcavity ring-down spectroscopy of jet-cooled free radicals and other species
Shenghai Wu, Patrick Dupré, Terry A. Miller
DOI: 10.1039/B518279D
Direct PEM fuel cell using “organic chemical hydrides” with zero-CO2 emission and low-crossover
Atsushi Fukuoka, Masaru Ichikawa
DOI: 10.1039/B518369C
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure 2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure](https://static.chemtradehub.com/structs/473/473924-63-9-973b.webp)



