Cryogenic abnormal thermal expansion properties of carbon-doped La(Fe,Si)13 compounds

Literature Information

Publication Date 2015-10-26
DOI 10.1039/C5CP03948G
Impact Factor 3.676
Authors

Rongjin Huang, Wei Wang, Laifeng Li


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Abstract

Recently, La(Fe,Si)13-based compounds have attracted much attention due to their isotropic and tunable abnormal thermal expansion (ATE) properties as well as bright prospects for practical applications. In this research, we have prepared cubic NaZn13-type carbon-doped La(Fe,Si)13 compounds by the arc-melting method, and their ATE and magnetic properties were investigated by means of variable-temperature X-ray diffraction, strain gauge and the physical property measurement system (PPMS). The experimental results indicate that both micro and macro negative thermal expansion (NTE) behaviors gradually weaken with the increase of interstitial carbon atoms. Moreover, the temperature region with the most remarkable NTE properties has been broadened and near zero thermal expansion (NZTE) behavior occurs in the bulk carbon-doped La(Fe,Si)13 compounds.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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