Self-reactions in the HCl+ (DCl+) + HCl system: a state-selective investigation of the role of rotation

Literature Information

Publication Date 2015-05-29
DOI 10.1039/C5CP02266E
Impact Factor 3.676
Authors

Till Uhlemann, Jens Wallauer, Karl-Michael Weitzel


View Original

Abstract

The self-reaction of state-selected HCl+ (DCl+) ions with HCl has been investigated in a guided ion beam setup. The absolute cross sections for proton transfer and deuteron transfer decrease with increasing center of mass collision energy, Ec.m.. The cross section for charge transfer (DCl+ + HCl) exhibits a maximum at Ec.m. = 0.5 eV. The cross section for PT and DT decrease significantly with increasing rotational angular momentum in the molecular ion, for the PT the cross section increases again for the highest angular momentum investigated. The rotational dependence of the cross section is rationalized by a simple model in which both the collision energy and part of the rotational energy are available for the reaction. The contribution of the rotation to the total energy available itself depends on the collision energy.

Related Literature

Bio-based hyperbranched epoxy resins: synthesis and recycling

Jiang Li, Dan Li, Yunke Ma, Shucun Zhou, Yu Wang, Daohong Zhang

2023-12-18 Review Article

DOI: 10.1039/D3CS00713H

Pursuing excitonic energy transfer with programmable DNA-based optical breadboards

Divita Mathur, Sebastián A. Díaz, Ryan D. Pensack, Bernard Yurke, Austin Biaggne, Joseph S. Melinger, William B. Knowlton, Igor L. Medintz

2023-10-24 Review Article

DOI: 10.1039/D0CS00936A

Multiconfigurational photodynamics simulations reveal the mechanism of photodecarbonylations of cyclopropenones in explicit aqueous environments

Daniel M. Adrion, Waruni V. Karunaratne, Steven A. Lopez

2023-11-10 Edge Article

DOI: 10.1039/D3SC03805J

Contents list

2023-12-11 Front/Back Matter

DOI: 10.1039/D3CS90099A

Virus-mimicking nanosystems: from design to biomedical applications

Hao-Yang Liu, Xiao Li, Zhi-Gang Wang

2023-11-06 Tutorial Review

DOI: 10.1039/D3CS00138E

On-site airborne pathogen detection for infection risk mitigation

Andrew J. deMello, Maosheng Yao, Junji Cao

2023-10-26 Review Article

DOI: 10.1039/D3CS00417A

Reversible Cl/Cl− redox in a spinel Mn3O4 electrode

Sean K. Sandstrom, Qiuyao Li, Yiming Sui, Mason Lyons, Chun-Wai Chang, Rui Zhang, Heng Jiang, Mingliang Yu, David Hoang, William F. Stickle, Huolin L. Xin, Zhenxing Feng, Xiulei Ji

2023-10-24 Edge Article

DOI: 10.1039/D3SC04545E

Bidirectional manipulation of iodine redox kinetics in aqueous Fe–I2 electrochemistry

Hong Zhang, Lin Fu, Wenli Zhang, Yupeng Yuan

2023-10-20 Edge Article

DOI: 10.1039/D3SC04853E

Chalcogen bonding catalysis

Govindasamy Sekar, Vysakh Venugopalan Nair, Jieping Zhu

2023-12-07 Tutorial Review

DOI: 10.1039/D3CS00503H

You might also like

Compound Q&A

What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?

(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...

23930-19-0(3alpha,5alpha)-3-Hy...
Compound Q&A

What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?

The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...

546141-56-44-Amino-6-chloro-2-p...
Compound Q&A

Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?

Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...

24472-88-6(2-Benzoylethyl)trim...
Compound Q&A

Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?

N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...

393-12-4N-[4-Nitro-3-(triflu...
Compound Q&A

Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?

There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...

4605-14-5N,N'-Bis(3-aminoprop...
Compound Q&A

What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?

When handling Aluminium trihexadecanoate, it is important to use appropriate per...

555-35-1Aluminium trihexadec...
Compound Q&A

What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?

(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...

52188-11-1(1,1-Dioxido-3-oxo-1...
Compound Q&A

Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?

Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...

3123-97-55,5-dimethyloxolan-2...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.