Visible light-induced hydrogen atom transfer trifluoromethylthiolation of aldehydes with bismuth catalyst
Literature Information
Publication Date
2023-12-08
DOI
10.1039/D3CC05048C
Impact Factor
6.222
Authors
Jun Dong, Zhuang Tang, Luqian Zou, Yongyun Zhou
View Original
Abstract
By using a combination of BiCl3 and TBACl as a ligand-to-metal charge transfer (LMCT) photocatalyst, hydrogen atom transfer trifluoromethylthiolation of aldehydes was achieved under visible light irradiation. The present method provides economical and operationally simple access to trifluoromethylthioesters using low toxicity and cost-effective bismuth catalysts under mild reaction conditions. Based on the radical trapping experiments, the direct conversion of aldehydes to acyl radicals via chlorine radicals as HAT reagents was proposed as the reaction mechanism.
Recommended Journals
Journal of Organometallic Chemistry
Journal of Medicinal Chemistry
Russian Chemical Reviews
Planta Medica
Science Progress
European Journal of Wood and Wood Products
Proceedings of the National Academy of Sciences of the United States of America
Organic Preparations and Procedures International
Kinetics and Catalysis
Journal of Heterocyclic Chemistry
Related Literature
The nature of chemical bonding in actinide and lanthanide ferrocyanides determined by X-ray absorption spectroscopy and density functional theory
Thomas Dumas, Dominique Guillaumont, Clara Fillaux, Andreas Scheinost, Philippe Moisy, Sébastien Petit, David K. Shuh, Tolek Tyliszczak
2015-12-16
Paper
DOI: 10.1039/C5CP05820A
Intensified effects of multi-Cu modification on the electronic properties of the modified base pairs containing hetero-ring-expanded pyrimidine bases
Yuxiang Bu, Huatian Wang
2015-12-21
Paper
DOI: 10.1039/C5CP06133D
High-performance lithium storage in an ultrafine manganese fluoride nanorod anode with enhanced electrochemical activation based on conversion reaction
Kun Rui, Zhaoyin Wen, Xiao Huang, Yan Lu, Jun Jin, Chen Shen
2016-01-04
Paper
DOI: 10.1039/C5CP07361H
Doping liquid crystals with nanoparticles. A computer simulation of the effects of nanoparticle shape
Silvia Orlandi, Erika Benini, Isabella Miglioli, Dean R. Evans, Victor Reshetnyak, Claudio Zannoni
2015-12-03
Paper
DOI: 10.1039/C5CP05754J
Global optimization of clusters of rigid molecules using the artificial bee colony algorithm
Jun Zhang, Michael Dolg
2015-12-16
Paper
DOI: 10.1039/C5CP06313B
White light emission from a two-component hybrid gel via an energy transfer process
Haichuang Lan, Zhenhua Li, Yueyuan Mao, Liming Chen, Yongquan Wu, Tao Yi
2015-11-10
Paper
DOI: 10.1039/C5CP05232G
Probing the microsolvation of a quaternary ion complex: gas phase vibrational spectroscopy of (NaSO4−)2(H2O)n=0–6, 8
Torsten Wende, Nadja Heine, Tara I. Yacovitch
2015-11-18
Paper
DOI: 10.1039/C5CP05762K
Towards better understanding of C60 organosols
Nikolay O. Mchedlov-Petrossyan, Nika N. Kamneva, Younis T. M. Al-Shuuchi, Andriy I. Marynin, Olexii S. Zozulia, Alexander P. Kryshtal, Vladimir K. Klochkov, Sergey V. Shekhovtsov
2015-12-07
Paper
DOI: 10.1039/C5CP06806A
Liquid–liquid equilibria of binary mixtures of a lipidic ionic liquid with hydrocarbons
Blane D. Green, Alexander J. Badini, Richard A. O'Brien, James H. Davis, Jr., Kevin N. West
2015-12-16
Paper
DOI: 10.1039/C5CP06101F
Photon management properties of rare-earth (Nd,Yb,Sm)-doped CeO2 films prepared by pulsed laser deposition
Matteo Balestrieri, Silviu Colis, Mathieu Gallart, Guy Schmerber, Paul Bazylewski, Gap Soo Chang, Marc Ziegler, Pierre Gilliot, Abdelilah Slaoui, Aziz Dinia
2015-12-07
Paper
DOI: 10.1039/C5CP04961J
You might also like
Compound Q&A
How should waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphenyl)-1H-pyrrolo[3,2-d]pyrimidine-2,4(3H,5H)-dione (CAS: 1346607-05-3) be handled?
Waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphe...
1346607-05-36-Chloro-5-(2'-hydro...
Compound Q&A
What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?
(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...
23930-19-0(3alpha,5alpha)-3-Hy...
Compound Q&A
What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?
The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...
546141-56-44-Amino-6-chloro-2-p...
Compound Q&A
Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?
Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...
24472-88-6(2-Benzoylethyl)trim...
Compound Q&A
Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?
N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...
393-12-4N-[4-Nitro-3-(triflu...
Compound Q&A
Are there alternatives to [(4R,5R,6S)-5-hydroxy-10-imino-3,7-dioxa-1,9-diazatricyclo[6.4.0.02,6]dodeca-8,11-dien-4-yl]methyl dihydrogen phosphate (CAS: 39679-56-6) in synthesis?
Alternative reagents such as other phosphates or similar functional groups can b...
39679-56-6[(4R,5R,6S)-5-hydrox...
Compound Q&A
Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?
There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...
4605-14-5N,N'-Bis(3-aminoprop...
Compound Q&A
What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?
When handling Aluminium trihexadecanoate, it is important to use appropriate per...
555-35-1Aluminium trihexadec...
Compound Q&A
What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?
(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...
52188-11-1(1,1-Dioxido-3-oxo-1...
Compound Q&A
Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?
Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...
3123-97-55,5-dimethyloxolan-2...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![1-[6-(1H-Imidazol-1-yl)-3-pyridinyl]methanamine structure](https://static.chemtradehub.com/structs/914/914637-08-4-8825.webp "1-[6-(1H-Imidazol-1-yl)-3-pyridinyl]methanamine structure")
![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp "(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure")
(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid
CAS Number:
1093085-91-6
Molecular Formula:
C18H25NO6
![N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure](https://static.chemtradehub.com/structs/234/23446-03-9-e1e5.webp "N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure")
N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine
CAS Number:
23446-03-9
Molecular Formula:
C12H22N2O5S
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.