Highly branched bolapolyphilic liquid crystals with a cubic A15 network at the triangle-square transition

Literature Information

Publication Date 2023-12-22
DOI 10.1039/D3CC05247H
Impact Factor 6.222
Authors

Christian Anders, Matthias Wagner, Mohamed Alaasar, Virginia-Marie Fischer, Rebecca Waldecker, Yangyang Zhao, Tianyi Tan, Yu Cao, Feng Liu, Carsten Tschierske


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Abstract

Rod-like bolapolyphiles with highly branched carbosilane-based side-chains self-assemble into several honeycomb structures if the oligo(p-phenylene ethynylene) core is polyfluorinated, whereas for the non-fluorinated series an A15 type cubic network of rod-bundles was observed instead, suggesting a brand new pathway for the transition between triangular and square honeycomb phases.

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