Criteria for solvate ionic liquids

Literature Information

Publication Date 2014-03-12
DOI 10.1039/C4CP00461B
Impact Factor 3.676
Authors

Toshihiko Mandai, Kazuki Yoshida, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe


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Abstract

Certain concentrated mixtures of salts and solvents are not simply “solutions” anymore, but they may be described as “ionic liquids”. In this perspective paper, we describe possible criteria for the new family of ionic liquids: “solvate” ionic liquids. This subclass of ionic liquids was originally proposed by Angell et al. in their recent review; however, their criteria remain to be debated. Concentrated mixtures of lithium salts and organic solvents are useful models for these solvate ionic liquids, and the effects of the salt concentration, types of solvents, and counter anions of the lithium salts on their structure and properties have been explored to enable contrast with traditional solutions, and to help determine whether a given mixture belongs to the solvate ionic liquid or not.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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