C2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends

Literature Information

Publication Date 2004-11-19
DOI 10.1039/B412599A
Impact Factor 6.222
Authors

Peter B. Hitchcock, Anthony G. Avent, Natalia Martsinovich, Pavel A. Troshin, Roger Taylor


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Abstract

Single crystal X-ray analysis shows the main (C2) isomer of C70F38 to contain three planar delocalised aromatic hexagons (two equivalent and one centred on the C2 axis), together with seven CC bonds (three pairs and one straddling the C2 axis); C70F38 is the first high addition level [70]fullerene derivative to be fully characterised, is the first to have equatorial addends, and is calculated to have high stability.

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