Reversible formation of excited states in intramolecular donor assisted chemiluminescence reactions of dioxetanes

Literature Information

Publication Date 2003-06-16
DOI 10.1039/B304245F
Impact Factor 6.222
Authors

Sharat Singh, Edwin F. Ullman


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Abstract

Data are presented requiring that the currently accepted CIEEL mechanism for the chemiluminescence of electron donor substituted dioxetanes be modified to include reversible thermal population of a dioxetane excited charge transfer state that undergoes ring scission with excited product formation which is accelerated by energy acceptors.

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