One-step facile synthesis of monodisperse raspberry-like P(S–MPS–AA) colloidal particles
Literature Information
Publication Date
2013-03-01
DOI
10.1039/C3PY21155J
Impact Factor
5.582
Authors
Yangyi Sun, Yuyong Yin, Min Chen, Shuxue Zhou, Limin Wu
View Original
Abstract
This paper presents a one-step procedure for the facile synthesis of monodisperse raspberry-like polymer colloidal particles by soap-free emulsion polymerization of styrene (S), acrylic acid (AA), and 3-(trimethoxysilyl)propyl methacrylate (MPS). In this method, when S, AA, and MPS are mixed with water and stirred at a certain temperature, raspberry-like P(S–MPS–AA) colloidal particles with uniform shapes and sizes could be obtained in a reliable manner. Both the core particles and the smaller corona particles of core surfaces were formed in situ. A mechanism of formation based on the second nucleation induced by MPS-enriched segments on the core surfaces is proposed.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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