Chemical conversion of biomass-derived hexose sugars to levulinic acid over sulfonic acid-functionalized graphene oxide catalysts
Literature Information
Ji-Woong Yoon, Dong Won Hwang, Harold H. Kung
Heterogeneous graphene oxide (GO)-based catalysts with sulfonic acid (SO3H) functional groups (GO–SO3H) were used for the selective decomposition of the hexose sugars, glucose and fructose into levulinic acid (LA), which has been used as a platform chemical for various value-added derivatives. The GO–SO3H catalysts gave high yields of around 78% for LA and showed good reuse compatibility with reliable performance. The chemical transformation patterns for hexose sugar decompositions are affected by the temperature, the density of acid sites, and the type of catalyst. The high catalytic performance of GO–SO3H was shown to result from the higher density of Brønsted acid sites in the GO, compared with the Lewis acid sites in other AC–SO3H catalysts. The morphology, surface characteristics, and other physiochemical properties were evaluated using several characterization techniques.
Recommended Journals
Related Literature
Aqueous MCRs of quaternary ammoniums, N-substituted formamides and sodium disulfide towards aryl thioamides
Zhou Zhou, Jin-Tao Yu, Yongnan Zhou, Yan Jiang, Jiang Cheng
DOI: 10.1039/C6QO00670A
Iodine(iii)-induced regioselective carbocyclization of terminal alkynes: a facile approach to prepare 1,1-diiodomethylene substituted cyclic compounds
Zeyu Wang, Jiang Zhong, Chen Zheng, Renhua Fan
DOI: 10.1039/C6QO00822D
A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines
Wei-Si Guo, Yuan-Chao Wang, Qian Dou, Li-Rong Wen, Ming Li
DOI: 10.1039/C6QO00739B
An efficient synthesis of fluoro-neplanocin A analogs using electrophilic fluorination and palladium-catalyzed dehydrosilylation
Dnyandev B. Jarhad, Min Hwan Jang, Young Sup Shin, Hong-Rae Kim, Young Eum Hyun, Ji-seong Yoon, Lak Shin Jeong
DOI: 10.1039/C9QO00099B
From glucose to enantiopure morpholino β-amino acid: a new tool for stabilizing γ-turns in peptides
Raffaella Bucci, Alessandro Contini, Francesca Clerici, Sara Pellegrino, Maria Luisa Gelmi
DOI: 10.1039/C8QO01116H
Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R
Dan Xu, Yanbang Li, Ning Lou
DOI: 10.1039/C7QO00098G
Tuning liquid crystalline phase behaviour in columnar crown ethers by sulfur substituents
Jochen Kirres, Katharina Schmitt, Iris Wurzbach, Frank Giesselmann, Sabine Ludwigs, Mark Ringenberg, Angelika Baro, Sabine Laschat
DOI: 10.1039/C7QO00077D
Quasi-planar diazadithio and diazodiseleno[8]circulenes: synthesis, structures and properties
Xiaodong Xiong, Chun-Lin Deng, Zhiming Li
DOI: 10.1039/C6QO00662K
A general synthesis of unnatural α-amino acids by iron-catalysed olefin–olefin coupling via generated radicals
Nadezhda V. Stoletova, Vladislav I. Kovalev, Tat'yana F. Savel'yeva, Victor I. Maleev
DOI: 10.1039/C9QO00108E
Nanocalipers as novel molecular scaffolds for carbon nanotubes
Gang Liu, Yuya Miyake, Naoki Komatsu
DOI: 10.1039/C7QO00158D
You might also like
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
Source Journal
Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.














