Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R
Literature Information
Publication Date
2017-02-16
DOI
10.1039/C7QO00098G
Impact Factor
5.281
Authors
Dan Xu, Yanbang Li, Ning Lou
View Original
Abstract
The selective insertion of a CH2 or NH group at the 5,6-junction on the C59N skeleton is achieved through the PCl5 induced reaction of a CH2OH or NHOH group on the cage to form [C59N(CH2)]R or [C59N(NH)]R, respectively. Spectroscopic data and single crystal X-ray diffraction structure analysis confirmed the 5,6-open homoazafullerene structure.
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Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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Molecular Formula:
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