Structural and spectroscopic characterization of potassium fluoroborohydrides
Literature Information
Richard H. Heyn, Ivan Saldan, Magnus H. Sørby, Christoph Frommen, Bjørnar Arstad, Aud M. Bougza, Helmer Fjellvåg, Bjørn C. Hauback
Mechanochemical reactions between KBH4 and KBF4 result in the formation of potassium fluoroborohydrides K(BHxF4−x) (x = 0–4), as determined by 11B and 19F solid state NMR. The materials maintain the cubic KBH4 structure. Thermogravimetric (TG) data for a ball-milled sample with KBH4 : KBF4 = 3 : 1 are consistent with only desorption of hydrogen.
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