In situ determination of the surface excess upon electrochemical sulfate adsorption on Au(111) films by surface plasmon resonance
Literature Information
For the independent and simultaneous characterization of electrochemical processes, we employ surface plasmon resonance (SPR) detection together with standard electrochemical methods. As a first test system we studied sulfate adsorption on Au(111). After careful calibration of the SPR signal we obtained submonolayer sensitivity on a millisecond time scale. The experimental data are simulated within the framework of a layer stack model of the optical interface. The sulfate adsorbate is simply described, employing the optical properties of sulfuric acid. The obtained potential dependent sulfate coverage is in reasonable agreement with independent results as presented in the literature.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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