Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution
Literature Information
T. J. A. Wolf, R. Radloff, P. Lang, A. Stolow, A.-N. Unterreiner
The photoinduced dynamics of the fully halogenated cyclopentadienes C5Cl6 and C5Br6 have been investigated in solution and gas phase by femtosecond time-resolved spectroscopy. Both in solution and in gas phase, homolytic dissociation into a halogen radical and a C5X5 (X = Cl, Br) radical was observed. In liquid phase, solvent-dependent formation of charge transfer complexes between geminate radicals was observed for the first time. These complexes were found to be surprisingly stable and offered the opportunity to follow the dynamics of specific radical pairs. In the case of C5Cl6 in trichloroethanol, a reaction of the chlorine radical with molecules from the solvent cage was observed.
Recommended Journals

Planta Medica

Israel Journal of Chemistry

Journal of Medicinal Chemistry

European Journal of Wood and Wood Products

Nature

Proceedings of the National Academy of Sciences of the United States of America

Pure and Applied Chemistry

Journal of Heterocyclic Chemistry

Helvetica Chimica Acta

Pharmacological Reviews
Related Literature
Molecular engineering of donor–acceptor sp2-carbon-linked covalent organic frameworks for enhancing photocatalytic hydrogen production
Mei Xu, Shanshan Yu, Wanru Li, Chuangye Li, Yukai Peng, Fengtao Yu
DOI: 10.1039/D3PY01069D
Reprocessable and chemically recyclable poly(acylhydrazone–imine) covalent adaptable networks with enhanced mechanical strength and creep resistance
Chunyang Bao, Jie Liu, Yanlong Yin, Zhirong Xin
DOI: 10.1039/D3PY01054F
Tailoring molecular weight distribution via polymer degradability
Yeonsu Kim, Cheoljae Kim
DOI: 10.1039/D3PY01153D
Levoglucosan and levoglucosenone as bio-based platforms for polymer synthesis
Melissa K. Stanfield, Rhiannon S. Terry, Jason A. Smith, Stuart C. Thickett
DOI: 10.1039/D3PY01019H
A combined computational and experimental study of metathesis and nucleophile-mediated exchange mechanisms in boronic ester-containing vitrimers
Jacopo Teotonico, Laura Ballester-Bayarri, Marta Ximenis
DOI: 10.1039/D3PY01047C
From RAFT emulsion polymerization to RAFT dispersion polymerization: a facile approach to tuning dispersities and behaviors of self-assembled block copolymers
Junpeng Cao, Yanling Li, Yingxin Tan
DOI: 10.1039/D3PY01006F
Influence of Mo modification on coaromatization coupling methanol with n-hexane over [Zn,Mo]/HZSM-5 catalysts
Bing Zhu, Haibo Li, Xue Wang, Subing Fan, Junmin Lv, Tian-sheng Zhao
DOI: 10.1039/D3RE00133D
3D printed filtration and separation devices with integrated membranes and no post-printing assembly
Tushar Garg, Kathryn E. Rankin
DOI: 10.1039/D3RE00245D
Selective dye adsorption by pH modulation on chemically modified nanopolyaniline by N-grafting of maleic acid
Sai Sushree Rath, Nehapadma Mohanty, Braja N. Patra
DOI: 10.1039/D3PY00968H
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure 5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure](https://static.chemtradehub.com/structs/251/251903-00-1-9cb1.webp)

![1-oxaspiro[4.4]nonan-6-one structure 1-oxaspiro[4.4]nonan-6-one structure](https://static.chemtradehub.com/structs/134/134179-01-4-e051.webp)

