Tailoring molecular weight distribution via polymer degradability
Literature Information
Yeonsu Kim, Cheoljae Kim
An alternative approach for controlling the polymer molecular weight distribution (MWD) was developed based on the degradation of precisely synthesized degradable long-chain polymers. The long-chain mother polymer was prepared via living cascade enyne metathesis polymerization and programmed monomer addition, and molecular-weight-controlled daughter polymers were obtained by degradation. We controlled the average molecular weight (Mn) and MWD at the targeted Mn by varying the degradable-to-nondegradable monomer feed ratio and employing programmed monomer addition, respectively.
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Polymer Chemistry

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