Organoboron star polymersvia arm-first RAFT polymerization: synthesis, luminescent behavior, and aqueous self-assembly
Literature Information
Publication Date
2012-01-03
DOI
10.1039/C2PY00556E
Impact Factor
5.582
Authors
Fei Cheng, Edward M. Bonder, Ami Doshi, Frieder Jäkle
View Original
Abstract
The first examples of organoboron star polymers were prepared by arm-first RAFT polymerization using a novel luminescent organoboron crosslinker in combination with PS, PNIPAM, P4VP, and PNIPAM-b-PS as linear polymer precursors. Well-defined star architectures with a luminescent core were successfully obtained as confirmed by GPC-MALLS, NMR, DLS, and TEM analysis. The PNIPAM-b-PS stars are amphiphilic and undergo self-assembly in water with formation of super-aggregates that exhibit strong green fluorescence. The P4VP stars lend themselves to further functionalization at the periphery.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
(S)-3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-2-phenylpropanoic acid
CAS Number:
1217663-60-9
Molecular Formula:
C24H21NO4
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