Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid

Literature Information

Publication Date 2012-01-11
DOI 10.1039/C2PY00541G
Impact Factor 5.582
Authors

Issam Blidi, Roland Geagea, Olivier Coutelier, Stéphane Mazières, Frédéric Violleau, Mathias Destarac


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Abstract

RAFT/MADIX polymerisation of vinylphosphonic acid (VPA) was controlled in water with an O-ethyl xanthate transfer agent. This represents the first example of reversible deactivation radical polymerisation of a monomer bearing an unprotected phosphonic acid function. Hence, macromolecular engineering of polyphosphonates can now be envisioned by directly polymerising VPA in water.

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