Synthesis of microporous polymers by Friedel–Crafts reaction of 1-bromoadamantane with aromatic compounds and their surface modification
Literature Information
Ho Lim, Min Chul Cha, Ji Young Chang
Adamantane-based microporous polymers were prepared by Friedel–Crafts reaction of 1-bromoadamantane with benzene, biphenyl and terphenyl and then post-functionalized with 4-nitrobenzoyl chloride. At 298 K, the CO2 uptake capacity of the functionalized polymers was increased by 18–25%, owing to the interaction between the nitro group and CO2.
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![4-[2-(3,4-Dihydro-2H-chromen-6-yl)-1,3-oxazol-5-yl]-1-(3-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}benzyl)pyridinium bromide structure 4-[2-(3,4-Dihydro-2H-chromen-6-yl)-1,3-oxazol-5-yl]-1-(3-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}benzyl)pyridinium bromide structure](https://static.chemtradehub.com/structs/155/155863-03-9-8183.webp)