Synthesis of microporous polymers by Friedel–Crafts reaction of 1-bromoadamantane with aromatic compounds and their surface modification

Literature Information

Publication Date 2012-02-16
DOI 10.1039/C2PY00511E
Impact Factor 5.582
Authors

Ho Lim, Min Chul Cha, Ji Young Chang


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Abstract

Adamantane-based microporous polymers were prepared by Friedel–Crafts reaction of 1-bromoadamantane with benzene, biphenyl and terphenyl and then post-functionalized with 4-nitrobenzoyl chloride. At 298 K, the CO2 uptake capacity of the functionalized polymers was increased by 18–25%, owing to the interaction between the nitro group and CO2.

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Polymer Chemistry

Polymer Chemistry
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