A novel hydrate of α-cyclodextrin crystallised under high-pressure conditions

Literature Information

Publication Date 2012-10-18
DOI 10.1039/C2CE26362A
Impact Factor 3.545
Authors

Rubén Granero-García, Fernando J. Lahoz, Sofiane Saouane, Francesca P. A. Fabbiani


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Abstract

The technique of high-pressure crystallisation from solution has been applied to the study of α-cyclodextrin hydrate formation. A previously unobserved hydrate, here termed Ib, has been obtained at 0.65 GPa and characterised by single-crystal X-ray diffraction using synchrotron radiation. This form exhibits a combination of structural features of other known hydrates and hydration states obtained by theoretical calculations but never found experimentally before.

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CrystEngComm

CrystEngComm
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Articles per Year: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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