Synthesis of multi-block copolymer stars using a simple iterative Cu(0)-mediated radical polymerization technique
Literature Information
Publication Date
2011-09-30
DOI
10.1039/C1PY00384D
Impact Factor
5.582
Authors
Cyrille Boyer, Aurelia Derveaux, Per B. Zetterlund, Michael R. Whittaker
View Original
Abstract
In this communication, we describe a simple and highly efficient route to well-defined multi-block star copolymers based on copper(0)-mediated living radical polymerization. The technique involves a core first approach using a multi-functional initiator in connection with iterative copper(0)-mediated radical polymerization steps. Importantly, purification is not required between the successive chain extension steps as complete monomer conversion is reached before the addition of each consecutive monomer type.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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