(R)-2-(Methylamino)propanoic acid hydrochloride
CAS Number:
1155878-14-0
Molecular Formula:
C4H10ClNO2
BF3·Et2O-mediated Friedel–Crafts C–H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors
Literature Information
Publication Date
2011-07-27
DOI
10.1039/C1PY00203A
Impact Factor
5.582
Authors
Zheng-Dong Liu, Yong-Zheng Chang, Chang-Jin Ou, Jin-Yi Lin, Ling-Hai Xie, Cheng-Rong Yin, Ming-Deng Yi, Yan Qian, Nai-En Shi, Wei Huang
View Original
Abstract
C–H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel–Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp "[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure")
[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
871332-68-2
Molecular Formula:
C11H15BClNO3
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