Efficient electrochemical polymerhalogenation using a thin-layered cell
Literature Information
Publication Date
2011-05-07
DOI
10.1039/C1PY00150G
Impact Factor
5.582
Authors
Shotaro Hayashi, Shinsuke Inagi, Toshio Fuchigami
View Original
Abstract
The electrochemical halogenation of polythiophene derivatives (PTs) such as poly(3-hexylthiophene) (PHT), poly(thiophene-alt-9,9-dioctylfluorene) (PTF) and poly(bithiophene-alt-9,9-dioctylfluorene) (PBT) was investigated using a thin-layered cell. The reactivity and the current efficiency of the electrochemical halogenation of polythiophene derivatives were markedly improved by using the thin-layered cell as compared to using a conventional beaker-type cell. Moreover, the use of the thin-layered cell reduces the amount of electrolytic solution required. In addition, the optical and electrochemical properties of the obtained polymers were significantly changed by the complete substitution of chlorine atoms onto the thiophene ring.
Related Literature
Simply accessible platinum(ii) complexes enabling alkene hydrosilylation at ppm catalyst loadings
Benon P. Maliszewski, Eleonora Casillo, Perrine Lambert, Catherine S. J. Cazin, Steven P. Nolan
2023-11-09
Communication
DOI: 10.1039/D3CC05033E
CO2 switchable adhesion of ionic polydimethylsiloxane elastomers
Masatoshi Tsunoda, Shoei Shimozaki, Rina Sawada, Shoichi Kutsumizu
2023-11-14
Communication
DOI: 10.1039/D3CC04575G
Beyond the formation: unveiling the atmospheric transformation of organosulfates via heterogeneous OH oxidation
Sze In Madeleine Ng
2023-10-30
Feature Article
DOI: 10.1039/D3CC03700B
Electrolyte-assisted low-voltage decomposition of Li2C2O4 for efficient cathode pre-lithiation in lithium-ion batteries
Rang Xiao, Cong Kang, Yang Ren, Jiyuan Jian, Binghan Cui, Geping Yin, Yulin Ma, Pengjian Zuo, Guokang Han, Chunyu Du
2023-10-31
Communication
DOI: 10.1039/D3CC04442D
Expedient C–H allylation of sulfoxonium ylides: merging C–H and C–C/C–het bond activation
Sharajit Saha, Hemanga Bhattacharyya, Pallab Karjee, Bijoy Debnath, Kshitiz Verma, Tharmalingam Punniyamurthy
2023-10-31
Communication
DOI: 10.1039/D3CC04507B
Rapid construction of Co/CoO/CoCH nanowire core/shell arrays for highly efficient hydrogen evolution reaction
Sihan Liu, Shuai Wang, Weiye Shi, Qin Zhou, Yan Zhang, Chunqing Huo, Shengjue Deng, Shiwei Lin
2023-11-10
Communication
DOI: 10.1039/D3CC04591A
Interface-mediated protein aggregation
Fei Tao, Qian Han, Peng Yang
2023-11-01
Feature Article
DOI: 10.1039/D3CC04311H
Solvation rules: aromatic interactions outcompete cation–π interactions in synthetic host–guest complexes in water
Gloria Tobajas-Curiel, Jeremy K. M. Sanders, Christopher A. Hunter
2023-11-13
Communication
DOI: 10.1039/D3CC04399A
Rapid building block-economic synthesis of long, multi-O-GalNAcylated MUC5AC tandem repeat peptides
Arseniy Galashov, Ekaterina Kazakova, Christian E. Stieger, Oliver Seitz
2023-12-18
Edge Article
DOI: 10.1039/D3SC05006H
A condition-tuned unorthodox approach to indole-3-carboxylic acids and anthranilic acids via carbon atom translocation
Arup Bhowmik, Koushik Naskar, Shantonu Roy, Sudip Karmakar, Writhabrata Sarkar, Imtiaj Mondal, Arindam Sana, Indubhusan Deb
2023-10-31
Communication
DOI: 10.1039/D3CC04443B
You might also like
Compound Q&A
What is 3-Fluoro-2-methylbenzylamine (CAS: 771573-36-5)?
3-Fluoro-2-methylbenzylamine is an organic compound with the CAS number 771573-3...
771573-36-53-Fluoro-2-methylben...
Compound Q&A
Is Tert-butyl 2-(oxetan-3-ylidene)acetate (CAS: 1207175-03-8) safe?
Tert-butyl 2-(oxetan-3-ylidene)acetate is considered safe for its intended uses ...
1207175-03-8Tert-butyl 2-(oxetan...
Compound Q&A
What precautions should be taken when handling 4-Acetyl-2-fluorobenzonitrile (CAS: 214760-18-6)?
Proper personal protective equipment (PPE) such as gloves, goggles, and a lab co...
214760-18-64-Acetyl-2-fluoroben...
Compound Q&A
How is 2-Ethyl-4-methyl-1,3-thiazole (CAS: 15679-12-6) typically synthesized?
2-Ethyl-4-methyl-1,3-thiazole is commonly synthesized via the reaction of thiour...
15679-12-62-Ethyl-4-methyl-1,3...
Compound Q&A
How should 5',5''-([2,2'-Bithiophene]-5,5'-diyl)bis(([1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid)) (CAS: 1227780-71-3) be stored?
This compound should be stored in a cool, dry place away from direct sunlight an...
1227780-71-35',5''''-([2,2'-Bith...
Compound Q&A
What regulatory guidelines apply to L-Lysine Acetate Salt (CAS: 52315-92-1)?
L-Lysine Acetate Salt (CAS: 52315-92-1) is subject to various regulatory guideli...
52315-92-1L-LYSINE ACETATE SAL...
Compound Q&A
Is 6-Fluoro-3-hydroxy-2-pyrazinecarboxamide (CAS: 259793-96-9) safe?
6-Fluoro-3-hydroxy-2-pyrazinecarboxamide (CAS: 259793-96-9) is generally conside...
259793-96-96-Fluoro-3-hydroxy-2...
Compound Q&A
What are the physical and chemical properties of 1,1'-Sulfonylbis(1H-imidazole) (CAS: 7189-69-7)?
1,1'-Sulfonylbis(1H-imidazole) is a crystalline solid with a molecular weight of...
7189-69-71,1'-Sulfonylbis(1H-...
Compound Q&A
What industries use 4-methyl-7-nitro-1H-indole-3-carbonitrile (CAS: 289483-82-5)?
4-Methyl-7-nitro-1H-indole-3-carbonitrile (CAS: 289483-82-5) is primarily used i...
289483-82-54-methyl-7-nitro-1H-...
Compound Q&A
How should waste containing 5-Bromo-3-indolyl-beta-galactoside (CAS: 97753-82-7) be handled?
Waste containing 5-Bromo-3-indolyl-beta-galactoside (CAS: 97753-82-7) should be ...
97753-82-75-Bromo-3-indolyl-be...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![trans,trans-4-n-Propyl-4-[4-(trifluoromethoxy)phenyl]bicyclohexyl structure](https://static.chemtradehub.com/structs/133/133937-72-1-25ef.webp "trans,trans-4-n-Propyl-4-[4-(trifluoromethoxy)phenyl]bicyclohexyl structure")
trans,trans-4-n-Propyl-4-[4-(trifluoromethoxy)phenyl]bicyclohexyl
CAS Number:
133937-72-1
Molecular Formula:
C22H31F3O
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.