Operando and in situ Raman studies of alumina-supported vanadium phosphatecatalysts in propane ammoxidation reaction: activity, selectivity and active phase formation

Literature Information

Publication Date 2011-10-12
DOI 10.1039/C1CP22608H
Impact Factor 3.676
Authors

Ewelina Mikolajska, Søren B. Rasmussen, Anna E. Lewandowska, Miguel A. Bañares


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Abstract

Alumina-supported VPO materials are efficient catalysts for acrylonitrile production by the propane ammoxidation reaction. In order to understand the structure–activity relationship and the nature of active sites, operando Raman-GC analyses follow the states of vanadium and phosphorous species on an alumina support during ammoxidation. These oxides were supported on γ-alumina by incipient wetness impregnation at a total V + P loading of two monolayers, which led to incipient formation of nanoscaled VPO crystallites possessing a high surface-to-volume ratio. Since catalysis occurs at the catalyst surface, which is related to the surface and outermost layers, this approach allows studying surface species phase transformations near the surface, and relates changes in activity and selectivity to variations in composition and structure. Dispersed surface V5+ species appear selective to acetonitrile and V4+ species would promote selectivity to acrylonitrile. This study suggests that V3+ is probably involved in redox processes during propane ammoxidation and that the balance between these vanadium species would be determined by activation process.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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