Benzyl 3-(aminomethyl)piperidine-1-carboxylate hydrochloride
CAS Number:
1186663-23-9
Molecular Formula:
C14H21ClN2O2
Detailed study of the reversible addition–fragmentation chain transfer polymerization and co-polymerization of 2-methacryloyloxyethyl phosphorylcholine
Literature Information
Publication Date
2010-11-11
DOI
10.1039/C0PY00300J
Impact Factor
5.582
Authors
Neha Bhuchar, Zhicheng Deng, Kazuhiko Ishihara, Ravin Narain
View Original
Abstract
In this paper, we report on a detailed study of the reversible addition–fragmentation chain transfer (RAFT) polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC). The RAFT polymerization conditions were carefully monitored and it was noted that well-defined homopolymers with ideal low polydispersity (Mw/Mn < 1.2) could be achieved in methanol using 4-cyanopentanoic acid dithiobenzoate (CTP) as a chain transfer agent and 4,4′-azobis(4-cyanovaleric acid) (ACVA) as an initiator. A series of well-defined block copolymers having a range of compositions and molecular weight were prepared using poly(MPC) as the macroCTA. Statistical MPC-based copolymers of biological relevance were also synthesized and characterized.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Ethyl 6-(trifluoromethyl)pyridazine-3-carboxylate
CAS Number:
1192155-06-8
Molecular Formula:
C8H7F3N2O2
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