Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals
Literature Information
Publication Date
2010-09-06
DOI
10.1039/C0PY00245C
Impact Factor
5.582
Authors
Elena Chernikova, Vladimir Golubev, Anatoly Filippov, Ching Yeh Lin, Michelle L. Coote
View Original
Abstract
Spin traps have been used to obtain the first direct experimental determination of the addition (5 × 106 L mol−1 s−1), fragmentation (8 × 10−3 s−1) and self-termination (6.5 × 102 L mol−1 s−1) rate coefficients in RAFT polymerization using the interaction of a tert-butyl radical with tert-butyl dithiobenzoate at ambient temperature as a model reaction.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
trans-2-(2-Methoxyphenyl)-5-oxotetrahydrofuran-3-carboxylic acid
CAS Number:
99226-02-5
Molecular Formula:
C12H12O5
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