High-resolution solid-state 13C μMAS NMR with long coherence life times

Literature Information

Publication Date 2010-11-12
DOI 10.1039/C0CP01929A
Impact Factor 3.676
Authors

Suresh K. Vasa, Hans Janssen, Ernst R. H. Van Eck, Arno P. M. Kentgens


View Original

Abstract

Longer coherence life times (i.e. smaller homogeneous linewidths) can be achieved for carbon resonances which are strongly coupled to protons with high rf field heteronuclear decoupling in micro magic angle spinning NMR. Better proton decoupling enhances the sensitivity and resolution of two-dimensional through-bond correlation experiments for mass-limited samples with uniform carbon labeling.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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