Ultrafast dynamics through conical intersections and intramolecular vibrational energy redistribution in styrene

Literature Information

Publication Date 2010-11-10
DOI 10.1039/C0CP01723J
Impact Factor 3.676
Authors

A. D. G. Nunn, R. S. Minns, R. Spesyvtsev, M. J. Bearpark, M. A. Robb, H. H. Fielding


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Abstract

We report a femtosecond time-resolved photoelectron spectroscopy (TRPES) investigation of internal conversion in the first two excited singlet electronic states of styrene. We find that radiationless decay through an S1/S0 conical intersection occurs on a timescale of ∼4 ps following direct excitation to S1 with 0.6 eV excess energy, but that the same process is significantly slower (∼20 ps) if it follows internal conversion from S2 to S1 after excitation to S2 with 0.3 eV excess energy (0.9 eV excess energy in S1).

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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