Neutron reflectivity studies of the free liquid surface of methylcyclohexane–perfluoromethylcyclohexane near the critical endpoint

Literature Information

Publication Date
DOI 10.1039/A904343H
Impact Factor 3.676
Authors


View Original

Abstract

The surface structure of the liquid mixture methylcyclohexane (MCH)–perfluoromethylcyclohexane (PFMCH) has been investigated by specular neutron reflectometry from 42 K below to 10 K above the upper critical solution temperature TUCS=46.13°C. The results have been interpreted in the light of the Abele′s layer model which indicates that the reflectivity throughout the experimental temperature range is satisfactorily represented by a model with two relatively thin layers interposed between the vapour phase and a well-characterised subphase. The twin-layer region is everywhere richer in PFMCH, the component of lower surface tension, than the immediate subphase and is thus regarded as an adsorbed layer. For TUCS

Related Literature

Photoluminescence from vibrational excited-states for organic molecules adsorbed on Si nanoparticles

M. Maeda, T. Matsumoto, H. Kobayashi

2017-07-24 Paper

DOI: 10.1039/C7CP01836C

Synergistically enhanced photocatalytic reduction of CO2 on N–Fe codoped BiVO4 under visible light irradiation

L. Zhang, X. Chen, Y. L. Liu, S. G. Xu, S. K. Cao

2017-07-27 Paper

DOI: 10.1039/C7CP03995F

Recognition of chiral zwitterionic interactions at nanoscale interfaces by chiroplasmonic nanosensors

Wenjing Zhao, Rong-Yao Wang, Hong Wei, Jingliang Li, Yinglu Ji, Xinxin Jiang, Xiaochun Wu, Xiangdong Zhang

2017-06-01 Paper

DOI: 10.1039/C7CP03004E

In- and Ga-based inorganic double perovskites with direct bandgaps for photovoltaic applications

Jun Dai, Liang Ma, Minggang Ju, Jinsong Huang

2017-07-18 Paper

DOI: 10.1039/C7CP03448B

Tunable AIEE fluorescence constructed from a triphenylamine luminogen containing quinoline – application in a reversible and tunable pH sensor

Mengmeng Zhang, Wen Yang, Tingfeng Gong, Weiqun Zhou, Renyu Xue

2017-07-18 Paper

DOI: 10.1039/C7CP03234J

Computational design of pH-switchable control agents for nitroxide mediated polymerization

Ganna Gryn’ova, Leesa M. Smith, Michelle L. Coote

2017-08-09 Paper

DOI: 10.1039/C7CP04337F

The excited-state decay mechanism of 2,4-dithiothymine in the gas phase, microsolvated surroundings, and aqueous solution

Bin-Bin Xie, Qian Wang, Wei-Wei Guo, Ganglong Cui

2017-02-16 Paper

DOI: 10.1039/C7CP00478H

Polarization transfer efficiency in PHIP experiments

M. Emondts, J. F. P. Colell, B. Blümich

2017-08-01 Communication

DOI: 10.1039/C7CP04296E

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.