Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

Literature Information

Publication Date 2009-09-15
DOI 10.1039/B912590F
Impact Factor 6.222
Authors

Alexander Paptchikhine, Pradeep Cheruku, Mattias Engman, Pher G. Andersson


View Original

Abstract

The first Ir-catalyzed asymmetric hydrogenations of vinyl boronates have been performed using low catalyst loadings (0.5 mol%) and pressure (as low as 1 bar). Good selectivities (76–98% ee) were obtained for a range of substrates.

Related Literature

Molecular recognition of cationic phenothiazinium and phenoxazinium dyes with π-extended 2′-deoxyadenosine nucleotides

Karina Mondragón-Vásquez, Hugo Morales-Rojas

2009-10-06 Communication

DOI: 10.1039/B913315A

Electrochemistry at carbon nanotubes: perspective and issues

Ioana Dumitrescu, Patrick R. Unwin, Julie V. Macpherson

2009-09-23 Feature Article

DOI: 10.1039/B909734A

Synthesis and structure of a magnesium–amidoborane complex and its role in catalytic formation of a new bis-aminoborane ligand

Jan Spielmann, Michael Bolte, Sjoerd Harder

2009-10-21 Communication

DOI: 10.1039/B914979A

A thiophen-thiooxorhodamine conjugate fluorescent probe for detecting mercury in aqueous media and living cells

Yi Zhou, Xue-Yan You, Yuan Fang, Ju-Ying Li, Ke Liu, Cheng Yao

2010-09-22 Communication

DOI: 10.1039/C0OB00452A

Hydroxylation of benzophenone with ammonium phosphomolybdate in the solid state via UV photoactivation

Mrinmoyee Basu, Suresh Sarkar, Surojit Pande, Subhra Jana, Arun Kumar Sinha, Sougata Sarkar, Mukul Pradhan, Anjali Pal, Tarasankar Pal

2009-10-15 Communication

DOI: 10.1039/B905718H

Syntheses of ylidenbutenolide-modified derivatives of peridinin and their stereochemical and spectral characteristics

Takayuki Kajikawa, Kazuyoshi Aoki, Takashi Iwashita, Dariusz M. Niedzwiedzki, Harry A. Frank, Shigeo Katsumura

2010-04-23 Communication

DOI: 10.1039/C002006K

Inside front cover

Front/Back Matter

DOI: 10.1039/C0OB90045A

Facile preparation of linear polystyrene-stabilized Pd nanoparticles in water

Atsushi Ohtaka, Takuto Teratani, Ryohei Fujii, Kanako Ikeshita, Osamu Shimomura

2009-10-15 Communication

DOI: 10.1039/B915039K

Sulfonic acid functionalized crystal-like mesoporous benzene–silica as a remarkable water-tolerant catalyst

Ayman Karam, João Carlos Alonso, Tsvetelina Ivanova Gerganova, Paula Ferreira, Nicolas Bion, Joël Barrault, François Jérôme

2009-10-06 Communication

DOI: 10.1039/B914689J

NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

Vijay Nair, Sreekumar Vellalath, Beneesh P. Babu, Vimal Varghese, Rony Rajan Paul, Eringathodi Suresh

2010-08-24 Paper

DOI: 10.1039/C0OB00180E

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.