PPh3-catalyzed unexpected α-addition reaction of 1-(o-hydroxyaryl)-1,3-diketones to terminal alkynoates: a straightforward synthesis of multifunctional vinylesters

Literature Information

Publication Date 2009-08-26
DOI 10.1039/B909279J
Impact Factor 6.222
Authors

Ling-Guo Meng, Bin Hu, Quan-Ping Wu, Mao Liang, Song Xue


View Original

Abstract

PPh3-catalyzed α-addition reactions of 1-(o-hydroxyaryl)-1,3-diketones to terminal alkynoates involving carbon–carbon bond cleavage to give multifunctional vinylesters are described.

Related Literature

Deazaflavins as mediators in light-driven cytochrome P450 catalyzed hydroxylations

Felipe E. Zilly, Andreas Taglieber, Frank Schulz, Frank Hollmann, Manfred T. Reetz

2009-10-14 Communication

DOI: 10.1039/B913863C

Site-specific incorporation of perylene into an N-terminally modified light-harvesting complex II‡

Kalina Peneva, Kristina Gundlach, Andreas Herrmann, Harald Paulsen, Klaus Müllen

2010-09-06 Communication

DOI: 10.1039/C0OB00492H

Effect of substituents of alloxazine derivatives on the selectivity and affinity for adenine in AP-site-containing DNA duplexes

Burki Rajendar, Arivazhagan Rajendran, Zhiqiang Ye, Eriko Kanai, Yusuke Sato, Marek Sikorski

2010-08-31 Paper

DOI: 10.1039/C0OB00057D

Inside front cover

Front/Back Matter

DOI: 10.1039/C0OB90045A

Long wavelength red fluorescent dyes from 3,5-diiodo-BODIPYs

Lijuan Jiao, Changjiang Yu, Timsy Uppal, Mingming Liu, Yan Li, Yunyou Zhou, Erhong Hao, Xiaoke Hu, M. Graça H. Vicente

2010-04-14 Communication

DOI: 10.1039/C001068E

Towards understanding secondary structure transitions: phosphorylation and metal coordination in model peptides

Malgorzata Broncel, Sara C. Wagner, Kerstin Paul, Christian P. R. Hackenberger, Beate Koksch

2010-03-29 Paper

DOI: 10.1039/C001458C

Electrochemistry at carbon nanotubes: perspective and issues

Ioana Dumitrescu, Patrick R. Unwin, Julie V. Macpherson

2009-09-23 Feature Article

DOI: 10.1039/B909734A

Controlled growth of novel hyper-branched nanostructures in nanoporous alumina membrane

Junping Zhang, Cynthia S. Day, David L. Carroll

2009-10-20 Communication

DOI: 10.1039/B913917F

A triple-stranded helicate and mesocate from the same metal and ligand

Zhan Zhang, David Dolphin

2009-10-21 Communication

DOI: 10.1039/B913231G

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.