An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

Literature Information

Publication Date 2009-05-13
DOI 10.1039/B907746D
Impact Factor 6.222
Authors

Elena Arceo, Peter Marsden, Robert G. Bergman, Jonathan A. Ellman


View Original

Abstract

An efficient 1,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass-derived polyols (glycerol and erythritol) that results in the conversion of the 1,2-dihydroxy group to a carbon窶田arbon double bond.

Related Literature

Molecular transport of proteins through nanoporous membranes fabricated by interferometric lithography

Roland Faller, Ahmet Palazoglu, Sonia E. Létant, Joseph W. Tringe, Pieter Stroeve

2012-11-14 Paper

DOI: 10.1039/C2CP43400H

A large sample volume magic angle spinning nuclear magnetic resonance probe for in situ investigations with constant flow of reactants

Jian Zhi Hu, Jesse A. Sears, Hardeep S. Mehta, Joseph J. Ford, Ja Hun Kwak, Kake Zhu, Yong Wang, Jun Liu, David W. Hoyt, Charles H. F. Peden

2011-10-24 Paper

DOI: 10.1039/C1CP22692D

Generic pathways to stability in concentrated protein mixtures

Veronique Trappe

2012-01-19 Paper

DOI: 10.1039/C2CP22558A

The trehalose coating effect on the internal protein dynamics

Christiane Hackel, Tatyana Zinkevich, Peter Belton, Anja Achilles, Detlef Reichert

2012-01-19 Paper

DOI: 10.1039/C2CP23098D

Quantum chemical study of the catalytic activation of methane by copper oxide and copper hydroxide cations

E. Rezabal, F. Ruipérez, J. M. Ugalde

2012-11-19 Paper

DOI: 10.1039/C2CP43544F

Interactions of the intact FsrC membrane histidine kinase with the tricyclic peptideinhibitor siamycin I revealed through synchrotron radiation circular dichroism

Mary K. Phillips-Jones, Shalini Edara, Jiro Nakayama, Rohanah Hussain, Giuliano Siligardi

2012-11-14 Communication

DOI: 10.1039/C2CP43722H

Spatial and temporal variation of surface-enhanced Raman scattering at Ag nanowires in aqueous solution

Daniel A. Clayton, Tyler E. McPherson, Shanlin Pan, Mingyang Chen, David A. Dixon, Dehong Hu

2012-11-14 Paper

DOI: 10.1039/C2CP43424E

Inside front cover

Front/Back Matter

DOI: 10.1039/C2CP90013K

Do anions influence the polarity of protic ionic liquids?

Shashi Kant Shukla, Nageshwar D. Khupse, Anil Kumar

2011-12-23 Paper

DOI: 10.1039/C2CP23256A

A donor–acceptor type organic dye connected with a quinoidal thiophene for dye-sensitized solar cells

Makoto Komatsu, Jotaro Nakazaki, Satoshi Uchida, Takaya Kubo, Hiroshi Segawa

2013-01-03 Paper

DOI: 10.1039/C2CP43598E

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.