Ion-tagged π-acidic alkeneligands promote Pd-catalysed allyl–aryl couplings in an ionic liquid
Literature Information
Ian J. S. Fairlamb, Amanda G. Jarvis, Adam F. Lee, Christian Müller, John M. Slattery, Robert J. Thatcher, Dieter Vogt, Adrian C. Whitwood
Ionic π-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been “doped” into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.
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