Synthesis and structure of [{N(CH2CH2NSiMe3)3}URe(η5-C5H5)2]: a heterobimetallic complex with an unsupported uranium–rhenium bond

Literature Information

Publication Date 2009-04-24
DOI 10.1039/B906554G
Impact Factor 6.222
Authors

Benedict M. Gardner, Jonathan McMaster, William Lewis, Stephen T. Liddle


View Original

Abstract

The first structurally authenticated molecular uranium–transition metal bond is reported; DFT studies show σ- and π-components in the U–Re bond and this is the first time that the latter component has been reported in an unsupported f-element–transition metal bond.

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