A comparison of infrared spectroscopic methods for the study of heterogeneous reactions occurring on atmospheric aerosol proxies
Literature Information
Deborah J. Last, Juan J. Nájera, Carl J. Percival, Andrew B. Horn
In this paper, the heterogeneous reaction between oleic acid and ozone has been studied using infrared spectroscopy in two distinctly different experimental configurations. The effect of the experiment on the observed products and rates of reaction is compared in order to derive a better understanding of some of the variations in oleic acid reaction rates reported by a range of researchers. One set of measurements is made using thin films of oleic acid in an attenuated total internal reflection configuration, and it is shown that a treatment in which the ATR evanescent wave is convolved with a moving reaction front is essential for the extraction of reliable kinetic data. The results are compared to similar measurements in a recently developed aerosol flow tube equipped with a cross-beam infrared spectroscopic probe. Rates of reaction in the aerosol phase are observed to be approximately 10 times faster and possible reasons for this discussed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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