Electrochemical selenocyclization of 2-ethynylanilines with diselenides: facile and efficient access to 3-selenylindoles
Literature Information
Mingyu Zhang, Zhenyu Luo, Xinye Tang, Linmin Yu, Jinglin Pei, Junlei Wang, Caicai Lu
An efficient electrochemical selenocyclization strategy for the synthesis of 3-selenylindoles from 2-ethynylanilines and diselenides has been developed in simple tube- or beaker-type undivided cells under ambient conditions. Notably, these sustainable transformations are completed within a short time with low equivalents of charges, diselenides and electrolytes, exhibiting a broad substrate scope with excellent functional group compatibility. Moreover, a gram-scale electrosynthesis and late-stage functionalization of complex molecules further demonstrate the practical synthetic potential of this facile electrochemical system.
Recommended Journals

Journal of Saudi Chemical Society

Russian Journal of Coordination Chemistry

Nature Medicine

Organic Process Research & Development

Current Opinion in Solid State & Materials Science

Journal of Peptide Science

Drug Discovery Today

Journal of Natural Medicines

Chemistry Education Research and Practice

Russian Journal of General Chemistry
Related Literature
π-Stacking between Casiopeinas® and DNA bases
Rodrigo Galindo-Murillo, Joseelyne Hernandez-Lima, Mayra González-Rendón, Lena Ruíz-Azuara, Rafael Moreno-Esparza
DOI: 10.1039/C1CP20183B
Temperature dependent structured absorption spectra of molecular chlorine
I. A. K. Young, C. Murray, C. M. Blaum, R. A. Cox, R. L. Jones, F. D. Pope
DOI: 10.1039/C1CP21337G
Oxygen-containing gas-phase diatomic trications and tetracations: ReOz+, NbOz+ and HfOz+ (z = 3, 4)
V. Brites, K. Franzreb, J. N. Harvey, S. G. Sayres, M. W. Ross, D. E. Blumling, A. W. Castleman, Jr., M. Hochlaf
DOI: 10.1039/C1CP21566C
Broadening of the derivative discontinuity in density functional theory
P. Schmitteckert
DOI: 10.1039/C1CP21247H
Structural, morphological, and kinetic studies of β-amyloid peptide aggregation on self-assembled monolayers
Qiuming Wang, Nilam Shah, Jun Zhao, Chengshan Wang, Chao Zhao, Lingyun Liu, Lingyan Li, Feimeng Zhou, Jie Zheng
DOI: 10.1039/C1CP21156K
Excitons in semiconducting carbon nanotubes: diameter-dependent photoluminescence spectra
Yoshihiko Kanemitsu
DOI: 10.1039/C1CP21235D
MnO2/TiN heterogeneous nanostructure design for electrochemical energy storage
Stefanie A. Sherrill, Jonathon Duay, Zhe Gui, Parag Banerjee, Gary W. Rubloff
DOI: 10.1039/C1CP21815H
Effect of surface chemical composition on the work function of silicon substrates modified by binary self-assembled monolayers
Che-Hung Kuo, Chi-Ping Liu, Szu-Hsian Lee, Hsun-Yun Chang, Wei-Chun Lin, Yun-Wen You, Hua-Yang Liao
DOI: 10.1039/C1CP20590K
Double layer capacitance of anode/solid-electrolyte interfaces
DOI: 10.1039/C1CP20508K
You might also like
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
Source Journal
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.
![2-(7,7-Difluorobicyclo[4.1.0]hept-1-yl)ethanamine structure 2-(7,7-Difluorobicyclo[4.1.0]hept-1-yl)ethanamine structure](https://static.chemtradehub.com/structs/209/2098065-08-6-ff24.webp)



![2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure 2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure](https://static.chemtradehub.com/structs/127/1279090-25-3-1b84.webp)