Preparation and structure of the unique silicon(iv) cation [SiF3(Me3tacn)]+
Literature Information
Publication Date
2009-02-10
DOI
10.1039/B822236C
Impact Factor
6.222
Authors
Fei Cheng, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster, Wenjian Zhang
View Original
Abstract
The trifluorosilicon(IV) cation [SiF3(Me3tacn)]+, isolated as salts with [SiF5]−, [B{3,5-(CF3)2C6H3}4]− or Cl−, is obtained by reaction of SiF4 with Me3tacn under anhydrous conditions, and compared with the tetrafluoro complexes [SiF4(tmeda)] and [SiF4{κ2-Me2N(CH2)2NMe(CH2)2NMe2(CH2Cl)}][SiF5] obtained with the acyclic di- and tri-amines.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Recommended Compounds
Oxalic acid compound with cyclohexylsulfamothioic O-acid (11)
CAS Number:
31895-22-4
Molecular Formula:
C7H13NO4S3
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