Vinylidenerutheniums with an electrostructurally-flexible NO ligand and their ruthenacyclobutene formation

Literature Information

Publication Date 2009-03-30
DOI 10.1039/B821561H
Impact Factor 6.222
Authors

Mamoru Yamaguchi, Yasuhiro Arikawa, Yoshimasa Nishimura, Keisuke Umakoshi, Masayoshi Onishi


View Original

Abstract

Vinylidene ruthenium complexes were prepared from trichloronitrosylbis(phosphine)rutheniums and terminal alkynes, subsequent cycloaddition of methyl propiolate to the vinylidene complexes giving rise to unusual ruthenacyclobutene species; in these transformations, an interesting electrostructurally-flexible behaviour of the NO ligand was observed.

Related Literature

An expeditious one-step entry to the tetracyclic core of integrastatins

C. V. Ramana, Challa Nageswara Reddy, Rajesh G. Gonnade

2008-05-12 Communication

DOI: 10.1039/B801755G

Valence isomer of a β-diketiminate-supported phosphinidene: a case of C–H activation and ring contraction

Zheng Lu, Michael Findlater, Alan H. Cowley

2007-05-08 Communication

DOI: 10.1039/B704266C

Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

Shelli R. Waetzig, Jon A. Tunge

2008-06-10 Communication

DOI: 10.1039/B806949B

A multi-stage growth model leading to high-yield production of carbon nanotubes

Yajun Tian, Huaixin Yang, Shuanglin Zhan, Yunfa Chen

2008-05-16 Communication

DOI: 10.1039/B801966E

Synthetic studies and biosynthetic speculation on marine alkaloid chartelline

Shigeo Kajii, Toshio Nishikawa, Minoru Isobe

2008-05-09 Communication

DOI: 10.1039/B803797C

Nickel-catalyzed cross-coupling reactions of benzylic zinc reagents with aromatic bromides, chlorides and tosylates

Matthias A. Schade, Albrecht Metzger, Stephan Hug, Paul Knochel

2008-04-24 Communication

DOI: 10.1039/B803072C

Synthesis and self-assembly of propeller-shaped amphiphilic molecules

Kyung-Soo Moon, Eunji Lee, Myongsoo Lee

2008-04-23 Communication

DOI: 10.1039/B801108G

Copper-mediated controlled radical ring-opening polymerization (RROP) of a vinylcycloalkane

Nikhil Kumar Singha, Amalin Kavitha, Prodip Sarker, Stephen Rimmer

2008-05-21 Communication

DOI: 10.1039/B801149D

Tetrameric molecular bowl assembled from glycoluril building blocks

Neng-Fang She, Xiang-Gao Meng, Meng Gao, An-Xin Wu, Lyle Isaacs

2008-04-04 Communication

DOI: 10.1039/B800785C

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.